 |
Journal articles
Sulfide determination in hydrothermal seawater samples using a vibrating gold micro-wire electrode in conjunction with stripping chronopotentiometry.
Abstract : A rapid electrochemical stripping chronopotentiometric procedure to determined sulfide in unaltered hydrothermal seawater samples is presented. Sulfide is deposited at -0.25V (vs Ag/AgCl, KCl 3M) at a vibrating gold microwire and then stripped through the application of a reductive constant current (typically -2μA). The hydrodynamic conditions are modulated by vibration allowing a short deposition step, which is shown here to be necessary to minimize H(2)S volatilization. The limit of detection (LOD) is 30nM after a deposition step of 7s. This LOD is in the same range as the most sensitive cathodic voltammetric technique using a mercury drop electrode and is well below those reported previously for other electrodes capable of being implemented in situ.
https://hal.univ-brest.fr/hal-00766675
Contributor : Adminhal Univbrestbu Connect in order to contact the contributor
Submitted on : Tuesday, December 18, 2012 - 4:07:00 PM
Last modification on : Tuesday, October 19, 2021 - 7:00:18 PM
Contributor : Adminhal Univbrestbu Connect in order to contact the contributor
Submitted on : Tuesday, December 18, 2012 - 4:07:00 PM
Last modification on : Tuesday, October 19, 2021 - 7:00:18 PM
Links full text
