Elucidation of Switching Mechanisms in Memristive Junctions Integrating a Iron(II)‐Ter Pyridine Diazoted Complex
Abstract
An original way of elaborating vertical metal/molecules/metal memristive junctions through diazonium electrografting of the organic layer and inkjet‐printed top electrodes is reported here. The molecule of interest is a Fe II coordination complex with ter‐pyridine ligands, having a diazonium anchoring group. The resulting junction exhibits a memristive behavior characterized by a high ON/OFF ratio and plasticity property. Through the application of advanced techniques such as UV–vis and Raman time‐resolved spectroelectrochemistry, the study demonstrates the significant role of switchable azo bonds derived from diazo electrografting in memristive behavior.
Domains
Chemical Sciences
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Adv Elect Materials - 2024 - Jubert Tomasso - Elucidation of Switching Mechanisms in Memristive Junctions Integrating a.pdf (1.93 Mo)
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