A Supramolecular Ladderlike Structure Formed by the Auto-Assembly of Benzene-1,3,5-triphosphonic Acid - Université de Bretagne Occidentale Accéder directement au contenu
Article Dans Une Revue Crystal Growth & Design Année : 2007

A Supramolecular Ladderlike Structure Formed by the Auto-Assembly of Benzene-1,3,5-triphosphonic Acid

Résumé

Benzene-1,3,5-triphosphonic acid 1, which is the phosphonic acid analogue of trimesic acid, forms a columnar packing in the solid state that is characterized by strong hydrogen bonds (contact distances O···O ranging from 2.55 to 2.60 Å) and π-stacking (d(Ar···Ar) = 3.89 and 3.69 Å) involving the aromatic rings, thus designing an organic supramolecular ladder structure by auto-assembly.

Domaines

Chimie organique
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Dates et versions

hal-01581263 , version 1 (04-09-2017)

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Gary B. Hix, Vincent Caignaert, Jean-Michel Rueff, Loïc Le Pluart, John E. Warren, et al.. A Supramolecular Ladderlike Structure Formed by the Auto-Assembly of Benzene-1,3,5-triphosphonic Acid. Crystal Growth & Design, 2007, 7 (2), pp.208 - 211. ⟨10.1021/cg060813k⟩. ⟨hal-01581263⟩
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