An Efficient and Straightforward Access to Sulfur Substituted [2.2]Paracyclophanes: Application to Stereoselective Sulfenate Salt Alkylation

Abstract : A straightforward and high-yielding access to various [2.2]paracyclophanes possessing a sulfur-based functional group is reported, the key step being a SEAr reaction mediated by a sulfonium salt. The versatility of the methodology was exemplified by an original application in sulfenate salt chemistry, from which a remarkable chirality transfer was observed.
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Article dans une revue
Organic Letters, American Chemical Society, 2008, 10 (6), pp.1271 - 1274. 〈10.1021/ol800161m〉
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Soumis le : vendredi 1 septembre 2017 - 15:26:20
Dernière modification le : jeudi 11 janvier 2018 - 06:17:06

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Jean-François Lohier, Florian Foucoin, Paul-Alain Jaffres, José I. Garcia, Jana Sopková−de Oliveira Santos, et al.. An Efficient and Straightforward Access to Sulfur Substituted [2.2]Paracyclophanes: Application to Stereoselective Sulfenate Salt Alkylation. Organic Letters, American Chemical Society, 2008, 10 (6), pp.1271 - 1274. 〈10.1021/ol800161m〉. 〈hal-01580460〉

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