First insights into the protonation of dissymetrically disubstituted di-iron azadithiolate models of the [FeFe]H2ases active site

Abstract : Dissymetrically disubstituted di-iron azadithiolate complexes [Fe2(CO)4(κ2-LL){μ-SCH2N(iPr)CH2S}] (LL = dppe, phen) protonate exclusively at the N atom of the bridge, like the hexacarbonyl precursor but in contrast to symmetrically disubstituted analogues; substitution of dppe for two CO groups noticeably increases the kinetics of the electrocatalytic proton reduction process.
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Article dans une revue
Chemical Communications, Royal Society of Chemistry, 2008, 〈10.1039/B801373J〉
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http://hal.univ-brest.fr/hal-01580431
Contributeur : Nicolas Renard <>
Soumis le : vendredi 1 septembre 2017 - 15:13:10
Dernière modification le : jeudi 11 janvier 2018 - 06:24:35

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Salah Ezzaher, Pierre-Yves Orain, Jean-François Capon, Frederic Gloaguen, François Y. Pétillon, et al.. First insights into the protonation of dissymetrically disubstituted di-iron azadithiolate models of the [FeFe]H2ases active site. Chemical Communications, Royal Society of Chemistry, 2008, 〈10.1039/B801373J〉. 〈hal-01580431〉

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