m-phosphonobenzoic acid and copper(II) as precursors of helical chain and lamellar hybrid materials

Abstract : A 1D helical-chain material Cu6(H2O)7(m-PO3C6H4CO2)41, characterized by a non-centrosymmetric crystal structure, and a 2D lamellar hybrid material Cu(H2O)(m-PO3C6H4CO2H) 2 have been synthesised starting from m-phosphonobenzoic acid and copper(II). The pH of the reaction media regulates the formation of either 1 or 2.
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http://hal.univ-brest.fr/hal-01578094
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Soumis le : lundi 28 août 2017 - 16:22:06
Dernière modification le : jeudi 11 janvier 2018 - 06:19:42

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Jean-Michel Rueff, Vincent Caignaert, André Leclaire, Charles Simon, Jean-Pierre Haelters, et al.. m-phosphonobenzoic acid and copper(II) as precursors of helical chain and lamellar hybrid materials. CrystEngComm, Royal Society of Chemistry, 2009, 11 (4), 〈http://pubs.rsc.org/en/content/articlelanding/2009/ce/b816132c#!divAbstract〉. 〈10.1039/B816132C〉. 〈hal-01578094〉

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