Small molecule mimics of hydrogenases: hydrides and redox

Abstract : This tutorial review is aimed at chemical scientists interested in understanding and exploiting the remarkable catalytic behavior of the hydrogenases. The key structural features are analyzed for the active sites of the two most important hydrogenases. Reactivity is emphasized, focusing on mechanism and catalysis. Through this analysis, gaps are identified in the synthesis of functional replicas of these fascinating and potentially useful enzymes.
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Article dans une revue
Chemical Society Reviews, Royal Society of Chemistry, 2009, 38 (1), pp.100 - 108. 〈http://pubs.rsc.org/en/Content/ArticleLanding/2009/CS/B801796B#!divAbstract〉. 〈10.1039/B801796B〉
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http://hal.univ-brest.fr/hal-01578063
Contributeur : Nicolas Renard <>
Soumis le : lundi 28 août 2017 - 16:09:25
Dernière modification le : jeudi 11 janvier 2018 - 06:17:06

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Frederic Gloaguen, Thomas B. Rauchfuss. Small molecule mimics of hydrogenases: hydrides and redox. Chemical Society Reviews, Royal Society of Chemistry, 2009, 38 (1), pp.100 - 108. 〈http://pubs.rsc.org/en/Content/ArticleLanding/2009/CS/B801796B#!divAbstract〉. 〈10.1039/B801796B〉. 〈hal-01578063〉

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