Multielectron-Transfer Templates via Consecutive Two-Electron Transformations: Iron-Sulfur Complexes Relevant to Biological Enzymes

Abstract : [FeFe] hydrogenase mimics: Two polynuclear iron–sulfur complexes (1 and 2; see figure) were prepared and structurally characterized. They are potentially effective and stable multielectron-transfer relays for mediating four- and six-electron transformations via a cascade of reversible two-electron redox steps with relatively narrow potential spans.
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Chemistry - A European Journal, Wiley-VCH Verlag, 2012, 18 (44), pp.13968 - 13973. 〈http://onlinelibrary.wiley.com/doi/10.1002/chem.201201326/abstract〉. 〈10.1002/chem.201201326〉
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http://hal.univ-brest.fr/hal-01556801
Contributeur : Nicolas Renard <>
Soumis le : mercredi 5 juillet 2017 - 15:35:40
Dernière modification le : jeudi 11 janvier 2018 - 06:17:06

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Lin Chen, Mei Wang, Frederic Gloaguen, Dehua Zheng, Peili Zhang, et al.. Multielectron-Transfer Templates via Consecutive Two-Electron Transformations: Iron-Sulfur Complexes Relevant to Biological Enzymes. Chemistry - A European Journal, Wiley-VCH Verlag, 2012, 18 (44), pp.13968 - 13973. 〈http://onlinelibrary.wiley.com/doi/10.1002/chem.201201326/abstract〉. 〈10.1002/chem.201201326〉. 〈hal-01556801〉

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