Recent advances in the chemistry of tris(thiolato) bridged cyclopentadienyl dimolybdenum complexes

Abstract : The chemistry of tris(thiolato) bridged dimolybdenum compounds in low oxidation states (mostly III) is considered. Various synthetic routes lead to chalcogenide-bridged dinuclear complexes of group 6 metals (mainly Mo). Extensive chemistry of these derivatives is reviewed. Their reactivity towards various reagents such as alkynes, isonitriles, nitriles, propargylic alcohols, azides, hydrazines, carbon disulfide…, demonstrates their ability for activation of small unsaturated molecules through new C–X (X = C, N, O, S…) bonds formation or cleavage.
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Coordination Chemistry Reviews, Elsevier, 2017, 331, pp.73 - 92. 〈10.1016/j.ccr.2016.10.004〉
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Contributeur : Philippe Schollhammer <>
Soumis le : samedi 18 novembre 2017 - 16:49:19
Dernière modification le : jeudi 11 janvier 2018 - 06:17:06

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Philippe Schollhammer, François Y. Pétillon, Jean Talarmin. Recent advances in the chemistry of tris(thiolato) bridged cyclopentadienyl dimolybdenum complexes. Coordination Chemistry Reviews, Elsevier, 2017, 331, pp.73 - 92. 〈10.1016/j.ccr.2016.10.004〉. 〈hal-01485537〉

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