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Article Dans Une Revue Coordination Chemistry Reviews Année : 2017

Recent advances in the chemistry of tris(thiolato) bridged cyclopentadienyl dimolybdenum complexes

Résumé

The chemistry of tris(thiolato) bridged dimolybdenum compounds in low oxidation states (mostly III) is considered. Various synthetic routes lead to chalcogenide-bridged dinuclear complexes of group 6 metals (mainly Mo). Extensive chemistry of these derivatives is reviewed. Their reactivity towards various reagents such as alkynes, isonitriles, nitriles, propargylic alcohols, azides, hydrazines, carbon disulfide…, demonstrates their ability for activation of small unsaturated molecules through new C–X (X = C, N, O, S…) bonds formation or cleavage.
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Dates et versions

hal-01485537 , version 1 (18-11-2017)

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Philippe P. Schollhammer, François Y. Pétillon, Jean Talarmin. Recent advances in the chemistry of tris(thiolato) bridged cyclopentadienyl dimolybdenum complexes. Coordination Chemistry Reviews, 2017, 331, pp.73 - 92. ⟨10.1016/j.ccr.2016.10.004⟩. ⟨hal-01485537⟩
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